Casablanca. I love the scene where they sing La Marseillaise. Wonderful. Talk about an adrenaline rush. And the rest of the movie isn't bad either.
Ok, obviously the task set here is an impossible one. To pick a favorite movie from so many that resonate with all of us?
So to make my choice I went to that scene in all my movie viewing that is the most magical for me, that I would miss the most.

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Casablanca good pick - for me it was the tension and how that "don't play it again Sam" and the "of all the gin joints in the world you had to walk into mine"
Joan of Arc - near the end of the movie - she is in prison and at this point you wonder if is she a victim of a vivid imagination and all of her life reacting to the trauma beset upon her sister that she witnessed. - Or- The scene - She is having her final conversations with God - It took the Catholic Church 500 years to figure it out when she was made a saint.
So definitely we can agree. But there are so many movies, so much enjoyment and memories to be had. I know I couldn't do a top ten, maybe a personal top 100 is possible. Thank goodness for Netflix...
http://en.wikipedia.org/wiki/AFI%27s_100_Years..._100_Movies_(10th_Anniversary_Edition)#The_List